Masahiko,
Developers will still be able to use the long canonical 'hex' UUID format for compatibility. But the short format is not a developer choice, but a convention. We mustn't allow a situation where 25% of systems use base32hex, 25% use Crocksford's Base32, 25% use base36, and 25% even use erroneously sorted base64. That's a very real nightmare. You, too, have every reason not to want to increase the number of built-in functions in PostgreSQL.
But here is a solution that I hope will satisfy everyone:
encode('019535d9-3df7-79fb-b466-fa907fa17f9e', 'uuid_to_base32hex') -> 06AJBM9TUTSVND36VA87V8BVJO
decode('06AJBM9TUTSVND36VA87V8BVJO', 'base32hex_to_uuid') -> 019535d9-3df7-79fb-b466-fa907fa17f9e
I don't see any real business need for UUID <-> bytea conversions.